Quick summary
Polarisation shows that light is a transverse wave. In polarised light, the electric vector vibrates in one particular direction. This topic covers methods of producing polarised light (reflection, refraction, double refraction, selective absorption), Malus's law, Brewster's law, Nicol prism, wave plates and optical activity.
Key points
- In unpolarised light the electric vector vibrates in all directions perpendicular to propagation. In plane-polarised light it vibrates in one plane only.
- Only transverse waves can be polarised; sound (longitudinal) cannot.
- Malus's law: intensity through an analyser varies as cos²θ.
- Brewster's law: at the polarising angle θₚ, the reflected light is completely plane-polarised, and tan θₚ = μ. At this angle the reflected and refracted rays are perpendicular.
- Double refraction: in calcite and quartz a ray splits into the ordinary (O) ray, which obeys Snell's law, and the extraordinary (E) ray, which does not. Both are plane-polarised at right angles to each other.
- Optic axis: direction in the crystal along which there is no double refraction.
- Calcite is a negative crystal (μₒ > μₑ); quartz is a positive crystal (μₑ > μₒ).
- Nicol prism: a calcite crystal cut and joined with Canada balsam; the O-ray is removed by total internal reflection and only the E-ray passes. Used as polariser and analyser.
- Quarter-wave plate introduces a path difference λ/4 (turns plane-polarised light at 45° into circularly polarised light). Half-wave plate introduces λ/2.
- Optical activity: some substances (quartz, sugar solution) rotate the plane of polarisation. Measured with a polarimeter.
Important terms
- Polariser / analyser – device that produces / tests polarised light.
- Polarising angle (ध्रुवण कोन) – angle of incidence giving fully polarised reflected light.
- Dextro-rotatory / laevo-rotatory – rotates the plane clockwise / anticlockwise (looking towards the source).
- Specific rotation – rotation by a 1 dm column of solution of unit concentration (1 g/cc).
Formulas
- Malus: I = I₀ cos²θ
- Brewster: μ = tan θₚ; θₚ + r = 90°
- Unpolarised light through a polaroid: I = I₀/2
- Quarter-wave plate thickness: t = λ/(4(μₒ − μₑ)) (use the magnitude of the difference); half-wave: t = λ/(2(μₒ − μₑ))
- Specific rotation: [α] = θ/(l × c) (l in dm, c in g/cc)
5 important questions
Q1. State Brewster's law.
When unpolarised light falls on a transparent surface at the polarising angle θₚ, the reflected light is completely plane-polarised and the refractive index μ = tan θₚ. Then the reflected and refracted rays are at 90°.
Q2. Find the polarising angle for glass of μ = 1.5.
θₚ = tan⁻¹(1.5) ≈ 56.3°. The angle of refraction is 90° − 56.3° = 33.7°.
Q3. Prove that at the polarising angle the reflected and refracted rays are perpendicular.
- Brewster: μ = tan θₚ = sin θₚ/cos θₚ.
- Snell: μ = sin θₚ/sin r.
- Equate: cos θₚ = sin r = cos(90° − r).
- So θₚ = 90° − r, i.e. θₚ + r = 90°.
- The angle between reflected and refracted rays = 180° − (θₚ + r) = 90°.
Q4. Calculate the thickness of a quartz quarter-wave plate for λ = 5893 Å (μₒ = 1.544, μₑ = 1.553).
- t = λ/(4(μₑ − μₒ)) (quartz is positive, so μₑ > μₒ).
- μₑ − μₒ = 0.009.
- t = 5893 × 10⁻¹⁰/(4 × 0.009) = 5.893 × 10⁻⁷/0.036.
- t ≈ 1.64 × 10⁻⁵ m ≈ 0.016 mm.
Q5. A 20 cm tube of sugar solution of concentration 0.1 g/cc rotates the plane of polarisation by 13°. Find the specific rotation. Also find the intensity through two polaroids at 60° if the incident light is unpolarised with intensity I₀.
- l = 20 cm = 2 dm, c = 0.1 g/cc.
- [α] = θ/(lc) = 13/(2 × 0.1) = 65° per dm per (g/cc).
- First polaroid: I₁ = I₀/2.
- Second (Malus): I₂ = I₁ cos²60° = (I₀/2)(1/4) = I₀/8.
Exam tip
In polarimeter numericals, change the tube length to decimetres. Draw the Nicol prism with the Canada balsam layer, O-ray and E-ray labelled — it is a common diagram question.